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Question

Which is the most stable halide of alkali metal?

A
Sodium fluoride
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B
Sodium bromide
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C
Sodium chloride
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D
Sodium iodide
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Solution

The correct option is A Sodium fluoride
Element MFMClMBrMI
Li-612 -398 -350 -271
Na-569 -400 -360 -288
K-563 -428 -392 -328
Rb-549 -423 -389 -329
Cs-531 -424 -395 -337
Standard enthalpies of formation in (kJ/mol) are given below.
The value decreases in the order: Fluoride > Chloride > Bromides > Iodide.
Thus, fluorides are the most stable while iodides are the least stable.

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