Which isomer of CrCl 3 -6 H 2 O is dark green in colour and forms one mole of AgCl with excess of AgNO 3 solution -A- -Cr H 2 O 5 Cl - Cl 2- H 2 OB- - Cr H 2 O 4 Cl 2- Cl 2- H 2 OC- - Cr H 2 O 3 Cl 3- 3 - H 2 OD- - Cr H 2 O 6- Cl 3

The correct option is B [Cr(H_2O)_4Cl_2]Cl_2.H_2O[Cr(H_2O)_4Cl_2]Cl.2H_2O ...

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Byju's Answer

Standard XII

Chemistry

Meso Compounds

Which isomer ...

Question

Which isomer of $C r C l_{3} .6 H_{2} O$ is dark green in colour and forms one mole of AgCl with excess of $A g N O_{3}$ solution -

[C r (H_{2} O)_{6}] C l_{3}

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[C r (H_{2} O)_{5} C l] C l_{2} . H_{2} O

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[C r (H_{2} O)_{4} C l_{2}] C l_{2} . H_{2} O

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[C r (H_{2} O)_{3} C l_{3}] 3. H_{2} O

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Solution

The correct option is C $[C r (H_{2} O)_{4} C l_{2}] C l_{2} . H_{2} O$
$[C r (H_{2} O)_{4} C l_{2}] C l .2 H_{2} O$

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Similar questions

Q. Which isomer of

C r C l_{3} .6 H_{2} O

is dark green in colour and forms one mole of

A g C l

with excess of

A g N O_{3}

solution -

Q. A six-coordinate complex of formula

C r C l_{6} .6 H_{2}

O is green in colour. A

0.1 M

solution of the complex when treated with excess of

A g N O_{3}

gave

28.7 g

of white precipitate. The formula of the complex would be:

When 1 mole of $C r C l_{3} .6 H_{2} O$ is treated with excess of $A g N O_{3},$ 3 moles of AgCl are obtained. The formula of the complex is
(a) $[C r C l_{3} (H_{2} O)_{3}] 3 H_{2} O$
(b) $[C r C l_{3} (H_{2} O)_{4}] C l_{2} .2 H_{2} O$
(c) $[C r C l_{3} (H_{2} O)_{5}] C l_{2} . H_{2} O$
(d) $[C r (H_{2} O)_{6}] C l_{3}$

Q. When 1 mole of

C r C l_{3} .6 H_{2} O

is treated with excess of

A g N O_{3}

, 2 mol of AgCl are obtained. The formula of the complex is

Q. What kind of isomerism exists between

[C r (H_{2} O)_{6}] C l_{3}

(violet) and

[C r (H_{2} O)_{5} C l] C l_{2} . H_{2} O

(greyish-green)?

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Which isomer of CrCl3.6H2O is dark green in colour and forms one mole of AgCl with excess of AgNO3 solution -

The correct option is C [Cr(H2O)4Cl2]Cl2.H2O[Cr(H2O)4Cl2]Cl.2H2O

Which isomer of $C r C l_{3} .6 H_{2} O$ is dark green in colour and forms one mole of AgCl with excess of $A g N O_{3}$ solution -

The correct option is C $[C r (H_{2} O)_{4} C l_{2}] C l_{2} . H_{2} O$
$[C r (H_{2} O)_{4} C l_{2}] C l .2 H_{2} O$