Which isomerism is shown by $[C o (N H_{3})_{6}] C l_{3}$ . Write name?

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Solution

$[C o (N H_{3})_{6}] C l_{3}$ shows solvate isomerism. There is exchange of ammonia molecules inside and outside co-ordination sphere.
$[C o (N H_{3})_{6}] C l_{3}$
$[C o (N H_{3})_{6} C l] C l_{2} \cdot N H_{3}$
$[C o (N H_{3})_{6} C l_{2}] C l \cdot 2 N H_{3}$
$[C o (N H_{3})_{6} C l_{3}] \cdot 3 N H_{3}$

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