Which kind of isomerism is exhibited by octahedral $[C o (N H_{3})_{4} B r_{2}] C l$ ?

Geometrical and ionization

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Geometrical and optical

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Optical and ionization

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Geometrical only

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Solution

The correct option is A Geometrical and ionization
The octahedral complex $[C o (N H_{3})_{4} B r_{2}] C l$ exhibits geometrical as well as ionization isomerism.
The geometrical isomers are cis and trans isomers.
The ionization isomers are $[C o (N H_{3})_{4} B r_{2}] C l a n d [C o (N H_{3})_{4} C l] B r_{2}$ .

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C o (N H_{3})_{4} B r_{2} C l ?

[C o {(e n)}_{2} N O_{2} B r] C l

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