The correct option is A Aluminium
The packing efficiency is the fraction of volume in a crystal
structure that is occupied by constituent particles (volume of space
occupied by the spheres/total volume). The majority of metals take on
either the hcp or bcc structure. Among the given metals Al occupies hexagonal close-packed (hcp) is having 0.74 packing efficiency and other metals form body-centered cubic (bcc) which has 0.68 packing efficiency.
Thus, Aluminium has the highest packing efficiency in comparison to Iron, Tungsten and Polonium.
Hence (C) is correct answer.