The correct option is B Fractional distillation
Fractional distillation is a separating technique used to separate the constituents of a liquid-liquid mixture having boiling point difference of less than 25oC by using a fractionating column.
Air is a homogeneous mixture of many different gases such as carbon dioxide, nitrogen, oxygen, argon, etc. Since these components have a difference in their boiling points less than 25oC, these are separated by the process of fractional distillation.