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B
K2SO4.Cr2(SO4)3.24H2O
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C
Na2SO4.Fe2(SO4)3.24H2O
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D
CuSO4.Al2(SO4)3.24H2O
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Solution
The correct option is DCuSO4.Al2(SO4)3.24H2O Double salts like metal double sulfate of aluminium is Alum. Copper sulfate with aluminium sulfate salt is not alum and it is toxic in nature.