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Question

Which of the elements has the greatest electron affinity among the halogens?


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Solution

  • Halogens have high electron affinity. Because they have a greater tendency to tendency to gain an additional electron to change into stable configuration.
  • Among halogens, electron affinity decreases from Chlorine(Cl) to iodine(I).
  • However, electron affinity of chlorine is unexpectedly higher than that of fluorine(F).
  • The size of F is is less compared to Cl.
  • The addition of electron on F produces high electron charge density and results strong electron- electron repulsion.
  • The repulsive force results in low electron affinity
  • The element with greatest electron affinity among halogens is Chlorine.

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