Which of the elements has the greatest electron affinity among the halogens?
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Solution
Halogens have high electron affinity. Because they have a greater tendency to tendency to gain an additional electron to change into stable configuration.
Among halogens, electron affinity decreases from Chlorine(Cl) to iodine(I).
However, electron affinity of chlorine is unexpectedly higher than that of fluorine(F).
The size of F is is less compared to Cl.
The addition of electron on F produces high electron charge density and results strong electron- electron repulsion.
The repulsive force results in low electron affinity
The element with greatest electron affinity among halogens is Chlorine.