The correct option is A Al2(SO4)3
There is a depression in freezing point of a solvent when a non-volatile solute is added to it.
ΔTf=iKfm
Since the molality is given, we need to look at the i value of the options to get the answer.
Al2(SO4)3 will have the greatest value of van 't Hoff factor (i=5), its solution would have the lowest freezing point.