Which of the following acts as the best coagulating agent for ferric hydroxide sol?
A
Potassium ferrocyanide
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B
Potassium chloride
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C
Potassium oxalate
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D
Aluminium chloride
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Solution
The correct option is A Potassium ferrocyanide
The process of settling of colloidal particles is called coagulation or precipitation of the sol.
The greater the valence of the flocculating ion added, the greater is its power to cause precipitation. This is known as a Hardy-Schulze rule.
Given, ferric hydroxide sol is a positive sol, and hence to coagulate it by using a negative sol.
Among all the options Pottasium ferrocyanide(K4Fe(CN)6.3H2O) the ion (Fe(CN)6)4− is having the maximum valence and hence acts as best coagulating agent for Ferric Hydroxide sol.