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Question

Which of the following acts as the best coagulating agent for ferric hydroxide sol?

A
Potassium ferrocyanide
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B
Potassium chloride
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C
Potassium oxalate
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D
Aluminium chloride
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Solution

The correct option is A Potassium ferrocyanide
  • The process of settling of colloidal particles is called coagulation or precipitation of the sol.
  • The greater the valence of the flocculating ion added, the greater is its power to cause precipitation. This is known as a Hardy-Schulze rule.
  • Given, ferric hydroxide sol is a positive sol, and hence to coagulate it by using a negative sol.
  • Among all the options Pottasium ferrocyanide(K4Fe(CN)6.3H2O) the ion (Fe(CN)6)4 is having the maximum valence and hence acts as best coagulating agent for Ferric Hydroxide sol.

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