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Question

Which of the following alkane cannot be made in good yield by wurtz reaction?

A
n-Heptane
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B
n-Butane
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C
n-Hexane
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D
n-octane
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Solution

The correct option is A n-Heptane
Wurtz Reaction is limited to the synthesis of symmetrical alkanes(even number of carbon atom). Heptane has odd number of carbon thus it cannot be prepared by wurtz reaction. Hence option (a) is correct.

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