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Which of the ...

Question

Which of the following alkanes is affected by $A l C l_{3}$ ?

C H_{4}

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C_{2} H_{6}

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C_{3} H_{8}

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C_{4} H_{10}

(n-butane)

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Solution

The correct option is B $C_{4} H_{10}$ (n-butane)
Alkanes on reaction with $A l C l_{3}$ produces isomers of the reacting alkane.
As $C H_{4}, C_{2} H_{6}, C_{3} H_{8}$ do not have any isomers but $C_{4} H_{10} (n - B u t n a e)$ has a isomer (iso-propane).
So, when $C_{4} H_{10} (n - B u t a n e)$ reacts with $A l C l_{3}$ , it will produce iso-propane.
Hence, Option "D" is the correct answer.

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