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Question

Which of the following alkenes is the most reactive towards cationic polymerisation?

A
CH2=CHCH3
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B
H2C=CHCl
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C
H2C=CHC6H5
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D
H2C=CHCO2CH3
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Solution

The correct option is D H2C=CHC6H5
The reactivity of alkenes towards cationic polymerisation increases as the stability of the intermediate carbocation increases.
In H2C=CHC6H5, the carbocation is stabilized by resonance, thus is most reactive towards cationic polymerisation.

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