Which of the following alkyl groups is more powerful electron donating group when they are attached to unsaturated carbon

- C H (C H_{3})_{2}

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- C H (C H_{3}) C_{2} H_{5}

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- C H_{3}

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- C H (C H_{3})_{3}

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Solution

The correct option is D $- C H (C H_{3})_{3}$
$-^{3^{0}} C H (C H_{3})_{3}$ is more powerful electron donating group due to the hyper conjugative effect (ie more no of $H$ on neighbouring $C - a t o m$ )

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The arrangement of ${(C H_{3})}_{3} C -$ , ${(C H_{3})}_{2} C H -$ , $C H_{3} C H_{2} -$ when attached to a benzene or an unsaturated group in increasing order of inductive effect effect is.

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Which of the following alkyl groups is more powerful electron donating group when they are attached to unsaturated carbon

The correct option is D −CH(CH3)3−30CH(CH3)3 is more powerful electron donating group due to the hyper conjugative effect (ie more no of H on neighbouring C−atom)

The correct option is D $- C H (C H_{3})_{3}$
$-^{3^{0}} C H (C H_{3})_{3}$ is more powerful electron donating group due to the hyper conjugative effect (ie more no of $H$ on neighbouring $C - a t o m$ )