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Question
Which of the following amines will give primary alcohol with NaNO2/Conc. HCl:
(a) CH3−CH2−C|CH3−NH2
(b) CH3−CH3|C|CH3−NH2
(c) CH3−C|CH3−CH2−CH2−NH2
(d) All of these
Which of the following amines will give primary alcohol with NaNO2/Conc. HCl:
(a) CH3−CH2−C|CH3−NH2
(b) CH3−CH3|C|CH3−NH2
(c) CH3−C|CH3−CH2−CH2−NH2
(d) All of these
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Solution
The correct option is C c
(c) CH3−C|CH3−CH2−CH2−NH2 For getting a primary alcohol, the aliphatic amine should have the –NH2 group on a primary carbon atom.
(c) CH3−C|CH3−CH2−CH2−NH2 For getting a primary alcohol, the aliphatic amine should have the –NH2 group on a primary carbon atom.
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