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Question

Which of the following anion has the lowest hydration enthalpy?

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Solution

Hydration enthalpyCharge on ionSize of ion
Since the charge on the anions are the same hence smaller the ion, higher the hydration enthalpy.

As we move down the group, the size of halogens increases. Thus, I will have the lowest hydration enthalpy.
Anion Hydration Enthalpy
(in kJ/mol)
F 515
Cl 381
Br 347
I 305

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