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Question

Which of the following anion(s) is/are interfering radicals?

A
BO33
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B
F
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C
PO34
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D
none of these
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Solution

The correct options are
A BO33
B F
D PO34
Interfering radicals are oxalate, tartrate, fluoride, borate and phosphate and they are anionic radicals.

These form complexes with IIIrd gr group reagent ammonium chloride and ammonium hydroxide. This leads to incomplete precipitation of IIIrd group cations and causes immature precipitation of IVth and Vth group cations in alkaline medium.

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