Which of the following aqueous solutions should have the highest boiling point?
A
1.0 M NaOH
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B
1.0 M Na2SO4
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C
1.0 M NH4NO3
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D
1.0 M KNO3
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Solution
The correct option is B 1.0 M Na2SO4 Assuming all the species undergo complete dissociation. [number of particles] ∝ [elevation in boiling point]. (a) 1.0 M NaOH→ 2 moles (a) 1.0 M Na2SO4→ 3 moles (a) 1.0 M NH4NO3→ 2 moles (a) 1.0 M KNO3→ 2 moles