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Question

Which of the following aqueous solutions will have the boiling point 102.2oC?
The molal elevation constant for water is 2.2K kg mol1.

A
1m CH3COOH
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B
1m NaCl
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C
1M NaCl
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D
1m Glucose
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Solution

The correct option is C 1m Glucose
We know that elevation in boiling point is given by,
ΔTb=iKbm
=i×2.2×m

ΔTb=102.2100=2.2oC
Comparing above equations-
i=1,m=1
Only possible for 1m Glucose solution.
Option D is correct.

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