The correct options are
C Dissolving conc. H2SO4 in water
1. Boiling of water would be an endothermic process because the system (water) is absorbing heat to turn into vapour. Hence both option 1 $ 3 are endothermic.
And the reverse process would therefore be exothermic.
2. Addition of Conc. acids to water is an exothermic reaction.