Which of the following are free radical reactions-2 CH 3 CH - CH 2- CI 2 CH 3 CH Cl CH 33 CH 3 CH - C H 2- HCI hr Cl - CH 2 CH - CH 24 CH 3 CH 3- Cl 2 hr - CI - CH 2 CH - CH 2A- Only d- - -C- a- b- dD- a- c- d

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Hybridisation in Carbon

Which of the ...

Question

Which of the following are free radical reactions?
$(1) C H_{3} C H = C H_{2} + H B R - ---------- \to C H_{3} C H_{2} C H_{2} - B r$
$(2) C H_{3} C H = C H_{2} + C I_{2} - --------- \to C H_{3} C H (C l) C H_{3}$
$(3) C H_{3} C H = C H_{2} + H C I - ---------- \to C l - C H_{2} C H = C H_{2}$
$(4) C H_{3} C H_{3} + C l_{2} h r - \to C I - C H_{2} C H = C H_{2}$

Only d

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a, c

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a, b, d

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a, c, d

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Solution

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C H_{3} C H = C H_{2}

C H_{3} C H = C H C H_{2} C H_{3}

C H_{3} C H = C H C H_{3}

The major product formed in the following reaction

$C H_{3} C H (C l) C H_{2} - C H_{2} O H a q . K O H - ---- \to$

$C H_{3} C H = C H_{2} + B . r \to C H_{3} . C H_{2} B r$

(C H_{3})_{3} C - C H_{2}^{+}

(C H_{3})_{3} C^{+}

C H_{3} C H_{2} C H_{2}^{+}

C H_{3} C H^{+} C H_{2} C H_{3}

C H_{2} = C = O, C H_{3} C H = C H_{2}, (C H_{3})_{2} C O, C H_{2} = C H C N, C_{6} H_{6}

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