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Question

Which of the following, are isoelectronic and isostructural ?

NO−3,CO2−3,ClO−3,SO3


A

NO3,CO23

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B

SO3,NO3

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C

ClO3,CO23

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D

CO23,SO3

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Solution

The correct option is A

NO3,CO23


No. of electrons in NO3=7+24+1=32

No. of electrons in CO23=6+24+2=32

Total no. of valence electrons in CO23=4+6×3+2=24

Now 24÷8=3(Q1)+O(R1)

Hybridisation of central atom in both cases is sp2. Hence they are isostructural also.


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