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Question

Which of the following are isoelectronic and isostructural NO−3,CO−23,ClO−3,SO3?

A
NO3,CO23
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B
SO3,NO3
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C
ClO3,CO23
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D
CO23,SO3
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Solution

The correct option is A NO3,CO23
Number of electrons in the compound is :
NO3=32e
CO23=32e
ClO3=42e
SO3=41e
Therefore, NO3 and CO23 are isoelectronic
The structures of both NO3 and CO23
is trigonal planar.
Therefore NO3andCO23 are isostructural also.

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