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Question

Which of the following are not ionic compounds?
(i) KCl
(ii) HCl
(iii) CCl4
(iv) NaCl

A
(i) and (ii)
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B
(ii) and (iii)
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C
(iii) and (iv)
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D
(i) and (iii)
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Solution

The correct option is B (ii) and (iii)
Hint: Ionic compounds are formed by the transfer of electrons.

Step 1:
Metals are good electron donors and non-metals are good electron acceptors. So, the bonds form between metal and non-metal are ionic bonds, and the compound formed is called an ionic or electrovalent compound.
Example: For KCl ionic compound where K is metal and Cl is non-metal.
KK++e ----- 1
12Cl2+eCl ----- 2
-----------------------------------------
Overall reaction: K+12Cl2KCl

Two non-metals form bonds by sharing electrons and such bonds are called covalent bonds and the compounds formed are called covalent compounds.

Step 2:
(i) KCl: K is a metal and Cl is a non-metal. So, the bond form between them is an ionic bond and the compound form is an ionic compound.
(ii) HCl: H is a non-metal and Cl is also a non-metal. So, the bond form between them is a covalent bond and the compound form is a covalent compound.
(iii) CCl4: C is a non-metal and Cl is also a non-metal. So, the bond form between them is a covalent bond and the compound form is a covalent compound.
(i) NaCl: Na is a metal and Cl is a non-metal. So, the bond form between them is an ionic bond and the compound form is an ionic compound.

Step 3:
So, among the given compounds, KCl and NaCl are ionic compounds, and HCl and CCl4 are covalent compounds.
Final step: Hence the correct option is (B): (ii) and (iii).

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