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Question

Which of the following aromatic compound gives sulphonation reaction very easily?

A
Chlorobenzene
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B
Nitrobenzene
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C
Toluene
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D
Benzene
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Solution

The correct option is B Toluene
Toluene gives a sulphonation reaction very quickly because sulphonation is ESR, so the ring must be electron-rich as nitro and chloro groups are electron-withdrawing groups due to which ring gets deactivated while the CH3 group is electron-donating makes ring electron-rich.

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