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Question

Which of the following arrangement of bond dissociation enthalpy of halogens is correct?
[1 Mark]

A
FF>ClCl>BrBr
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B
FF<ClCl<BrBr
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C
FF>ClCl<BrBr
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D
FF<BrBr<ClCl
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Solution

The correct option is D FF<BrBr<ClCl
Bond energy is inversely dependent on bond length. The order of bond length is Br2>Cl2>F2.
Hence, the order of bond energy should Br2<Cl2<F2. But bond dissociation enthalpy of F2 is least because of small size of F2 and large inter-electronic repulsions.
Thus, order of bond energy is FF<BrBr<ClCl.

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