The correct option is C 1, 2 and 4
A homologous series is a series of compounds in which each member differ from the previous/next member by CH2 or 14 mass units and have the same functional group.
1, 2 and 4 have same functional group (-COOH), so they are homologous in nature. C2H6 and C3H6 are neither homologous with 1, 2 and 4 nor with each other.