Synthesis of Aldehydes and Ketones Using Carboxylic Acid and Its Derivatives
Which of the ...
Question
Which of the following can be used to differentiate between aldehyde and ketone?
A
Ammoniacal AgNO3
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B
Ammoniacal AgNO3 in presence of tartarate ion
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C
I2 in the presence of base
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D
Ammoniacal AgNO3 in the presence of citrate ion
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Solution
The correct option is B Ammoniacal AgNO3 Aldehydes are oxidised by weak oxidising agents like Tollen's reagent (which is ammoniacal AgNO3) but ketones cannot be oxidised by them. Ketone + Tollen's reagent ⟶ no reaction.