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Question

Which of the following can show Frenkel as well as Schottky defect?

A
AgCl
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B
AgBr
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C
NaCl
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D
NaBr
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Solution

The correct option is B AgBr

Frenkel Defect is generally seen in those ionic solids in which there is a large difference in the size of cations and anions.

A Schottky defect is seen in the crystals (ionic solids) in which there is a small difference in the size of cations and anions.

Since, in AgBr, the size of cations and anions are such that it lies intermediate to value that is sufficient to show Frenkel Defect or Schottky Defect. So, it shows both defects.


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