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Question

Which of the following cannot form stable complexes?

A
Lanthanides
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B
Actinides
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C
Transition elements
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D
Iron
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Solution

The correct option is A Lanthanides
In lanthanides 4fsubshell shielded by 5d and 6s orbitals ,so f orbitals do not participate in bonding, they do not form stable complex. However in actinides 5f orbitals extends outwards and participate in bonding. They form stable complex .d - blocks element forms complex frequently too. Hence answer is A.

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