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Question

Which of the following chemical reactions depicts the oxidising behaviour of H2SO4?

A
2HI+H2SO4I2+SO2+2H2O
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B
Ca(OH)2+H2SO4CaSO4+2H2O
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C
NaCl+H2SO4NaHSO4+HCl
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D
2PCl5+H2SO42POCl3+2HCl+SO2Cl2
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Solution

The correct option is C 2HI+H2SO4I2+SO2+2H2O
In reaction A sulphur decreases its oxidation state from +6 in H2SO4 to +4 in SO2 and iodine increases its oxidation state from -1 in HI to 0 in I2.So H2SO4 acts as oxidising agent and I2 acts as reducing agent.
In reaction B, C and D sulphur do not decrease its oxidation state so H2SO4 does not act as oxidizing agent.
So only reaction A depicts the oxidizing behavior of H2SO4.

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