Option (d), Silver nitrate solution and copper
In a displacement reaction, a more reactive metal displaces a less reactive metal from its salt solution.
The reactivity of the metals given in the options is Sodium>Magnesium>Iron>Copper>Silver
Silver nitrate and copper metal undergo displacement reaction as copper is more reactive than silver. Hence, it displaces silver from silver nitrate solution to form copper nitrate solution. The reaction involved is:
Copper+Silver nitrate→Copper nitrate+Silver