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Question

which of the following combinations illustrates the law of multiple proportions and why:
a)N2O4,N2O
b)NaCl,NaBr
c)PCl3,PH3
​d)CS2,CO2

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Solution

The first one represent the law of multiple proportion.
For a given mass of an element, the masses of other elements come in the ratio of small integer.

Here N2O4​ and N2O has 1 part of nitrogen combine with oxygen in a ratio of 4 : 1

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