Which of the following complexes exhibits the highest paramagnetic behaviour ? (At. nos. Ti =22, V = 23, Fe = 26, Co= 27) Options: 1. [Co(OX)2(OH)2] – 2. [Ti(NH3)6]3+ 3. [V (gly)2(OH)2(NH3)2]+ 4. [Fe(en) (bpy) (NH3)2]2+

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T i = 22, C r = 24, C o = 27, Z n = 30

[A t . n o . T i = 22, C r = 24, C o = 27, Z n = 30]

V^{3 +}, F e^{2 +}, V^{4 +}, T i^{2 +}

Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour?

(Atomic Numbers: $C r = 24; M n = 25; F e = 26; C o = 27$ )

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S c^{3 +}, V^{3 +}, T i^{4 +}, M n^{2 +}

S c = 21, V = 23, T i = 22, M n = 25

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