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Question

Which of the following compound will evolve H2 gas when reacts with alkali metals?

A
H2C=CH2
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B
ROR
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C
RCH3
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D
ROH
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Solution

The correct option is D ROH
Alcohols when reacting with sodium metal evolution of hydrogen gas takes place. For example ethyl alcohol (ethanol) when reacting with sodium metal, the formation of sodium ethoxide and hydrogen gas takes place. It can be shown by the following reaction.
2ROHalcohol+2Na2RONa+sodium alkoxide+H2(g)

2ROHEthanol+2Na2RONa+sodium ethoxide+H2(g)

Hence, option D is correct.

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