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Question

Which of the following compound will undergo self-aldol condensation in the presence of cold dilute alkali?

A
C6H5CHO
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B
CH3CH2CHO
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C
HCCCHO
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D
CH2=CHCHO
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Solution

The correct option is B CH3CH2CHO
An aldol condensation is a condensation reaction in which an enol or an enolate ion reacts with a carbonyl compound to form a β-hydroxyaldehyde or β-hydroxyketone, followed by dehydration to an α,β-unsaturated aldehyde.
Aldol condensation occurs in aldehydes having α-hydrogen.
Only b has α-hydrogen thus it will undergoe aldol condensation.

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