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Question

Which of the following compounds can yield only one monochlorinated product upon free radical chlorination?

A
2, 2-Dimethyipropane
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B
2-Methylpropane
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C
2-Methylbutane
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D
n-Butane
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Solution

The correct option is A 2, 2-Dimethyipropane
Free radical chlorination of alkanes gives a complex mixture of isomeric mono- polyhaloalkanes which is difficult to separate as pure compounds. So the yield of any one compound is low. Therefore 2, 2 Dimethyipropane is the compound that can yeild only one monochlorinated product upon free radical chlorination.

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