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Question

Which of the following compounds cannot be prepared singly by the Wurtz reaction?

A
C2H6
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B
(CH3)2CHCH3
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C
CH3CH2CH2CH3
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D
All of the above can be prepared
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Solution

The correct option is B (CH3)2CHCH3
(CH3)2CHCH3 cannot be prepared singly by the Wurtz reaction. Unsymmetrical alkanes cannot be suitably obtained by this method. A mixture of two different alkyl halides is heated with sodium metal, three different alkanes will be produced.

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