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Question

Which of the following compounds favours SN2 mechanism?

A
CH3CH2Br
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B
CH3OCH2Br
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C
C6H5COCH2Br
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D
CH3C(CH3)2CH2Br
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Solution

The correct option is C C6H5COCH2Br
SN2 mechanism favours by formation of unstable carbocation.
Among all given compounds, C6H5COCH2Br forms least stable carbocation due to carbonyl group at alpha position of carbon atom (carbocation forms will be unstable due to resonance and -M effect of carbonyl group).
So it favours SN2 mechanism most.

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