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Question

Which of the following compounds gives yellow precipitate with I2 and alkali?

A
CH3OH
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B
CH3CH2CH2OH
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C
C2H5OC2H5
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D
CH3CH2OH
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Solution

The correct option is D CH3CH2OH
From iodoform reaction, it can be seen that it is given by
2-alkanols CH3OH|CHR or by methyl ketones CH3O||CR.
2-Alkanols are easily oxidized to methyl ketones which further give the iodoform formation indicated by the yellow precipitate formation.

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