Which of the following compounds gives yellow precipitate with I2 and alkali?
A
CH3OH
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B
CH3CH2CH2OH
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C
C2H5OC2H5
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D
CH3CH2OH
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Solution
The correct option is DCH3CH2OH From iodoform reaction, it can be seen that it is given by 2-alkanols ⎛⎜⎝CH3−OH|CH−R⎞⎟⎠ or by methyl ketones ⎡⎢⎣CH3−O||C−R⎤⎥⎦.
2-Alkanols are easily oxidized to methyl ketones which further give the iodoform formation indicated by the yellow precipitate formation.