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Question

Which of the following compounds has the highest enol content?

A
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B
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C
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D
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Solution

The correct option is B
Keto form is more stable than enol form because CO double bond is stronger than CC double bond.


a) Enol form is antiaromatic. Hence it has a major keto content.


b) Enol form is aromatic. Hence it has the highest enol content.


c) The enol form does not have any stabilization. Hence it has a higher keto content.


d) The enol form is antiaromatic and hence tends to remain as the keto form.

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