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Question

Which of the following compounds have highest melting point?
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A
Only I
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B
Only II
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C
I and II
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D
II and III
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Solution

The correct option is B Only II
Compound II is most symmetrical because it has both CH3 groups and Cl atoms p to each other. Therefore, it fits in the crystal lattice better than the other two isomers and hence it has high melting point.

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