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Question

Which of the following compounds is soluble in benzene but almost insoluble in water?

A
C2H5OH
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B
CH3CO2H
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C
CH3CHO
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D
C6H5NO2
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Solution

The correct option is D C6H5NO2
Nitrobezene C6H5NO2 is soluble in benzene but almost insoluble in water. Nitrobenzene is structurally similar to benzene. The solubility is based on the principal, 'like dissolves like'. Other compounds make a hydrogen bond with water and are more soluble than nitrobenzene.

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