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Question

Which of the following compounds of elements in group IV is expected to be least ionic?

A
PbCl2
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B
PbCl4
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C
CCl4
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D
SiCl4
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Solution

The correct option is D CCl4
Polarising power of an ion is inversely proportional to ionic character.

C4+ has maximum polarising power out of Pb2+,Pb4+,Si4+.

So, CCl4 is least ionic. Smaller the size of cation, higher is the polarization power.

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