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Question

Which of the following compounds possesses Lewis acid character?

A
AlF3
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B
SiF4
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C
PF5
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D
BF3
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Solution

The correct options are
B SiF4
C PF5
D BF3
AlF3 is ionic in nature. It has completed its octet. Hence, it cannot act as lewis acid.
BF3 has incomplete octet. So, it can accept an electron pair and act as lewis acid.
SiF4 and PF5 contain empty d orbitals. Hence, they can accept an electron pair and can act as lewis acids.

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