Which of the following compounds reduce(s) ammoniacal silver nitrate solution?
$C_{6} H_{5} C H O$
$C H_{3} C H_{2} C H O$
$C H_{3} C H_{2} O H$
$C H_{3} C H (O H) C O C H_{3}$

C H_{3} C H (O H) C O C H_{3}, C H_{3} C H_{2} C H O, C_{6} H_{5} C H O

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C H_{3} C H_{2} O H, C_{6} H_{5} C H O, C H_{3} C H (O H) C O C H_{3}

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C H_{3} C H_{2} O H, C H_{3} C H_{2} C H O, C H_{3} C H (O H) C O C H_{3}

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C_{6} H_{5} C H O, C H_{3} C H_{2} C H O

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Solution

The correct option is D $C_{6} H_{5} C H O, C H_{3} C H_{2} C H O$
Both aliphatic and aromatic aldehydes give Tollen's test. $α$ -hydroxy ketones (termnal) are also oxidised by Tollen's reagent. Thus correct option is (d).

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