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Question

Which of the following compounds shows both Frenkel and Schottky defects:

A
NaCl
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B
AgCl
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C
AgBr
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D
KCl
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Solution

The correct option is C AgBr
Schottky defect is shown in AgBr because cations and anions both get out of the lattice. Ag+ is quite small which is why it occupies interstitial sites easily - this is the Frenkel defect.

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