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Question

Which of the following compounds shows strongest hydrogen bonding?

A
HF
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B
H2O
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C
NH3
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D
CH3OH
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Solution

The correct option is A HF
Among the F, O and N , Fluorine has the higher value of electronegativity, this is the reason that fluorine can form the strongest hydrogen bond with the H atom of another molecule.
Just take an idea from the value of energy of hydrogen bond that is formed with HF, H2O and NH3

HF10kcal/mol
H2O 7Kcal/mol
NH3 2Kcal/mol
means to break the hydrogen of one mole HF molecules, 10Kcal energy is required.
So the correct option is [A].




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