Which of the following compounds will exhibit cis−trans (geometrical ) isomerism?
A
2-butene
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B
2-butyne
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C
2-butanol
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D
butanal
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Solution
The correct option is A 2-butene The restricted rotation of an atom or groups around the doubly bonded carbon gives different geometries of a compound. Such compounds are called geometrical isomers. This isomerism is also known as cis-trans isomerism. The compounds with each doubly bonded carbon attached to two different groups exhibit cis-trans isomerism. However, even though there is restricted rotation for triple bond, alkynes do not exhibit geometrical isomerism, since the triply bonded carbons are attached to one group each only.