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Question

Which of the following compounds will give butanone on oxidation with alkaline KMnO4 solution?

A
None of these
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B
Butan 2ol
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C
Butan 1ol
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D
Both of these
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Solution

The correct option is B Butan 2ol
Oxidation using alkaline KMnO4

Alkaline KMnO4 is a strong oxidising agent that coverts primary alcohols to carboxylic acid and secondary alcohols to ketones.

Analysing the options

Option (A)

When alkaline KMnO4 reacts with primary alcohol, it oxidises the primary alcohol to a carboxylic acid.


Option (B)

When alkaline KMnO4 react with secondary alcohol, it oxidises the secondary alcohol to a ketone.



Hence, option B is the correct answer.

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